Evaluation of Bioavailability and Partitioning of Aluminum in Sediment Samples of Different Ecosystems by Modified Sequential Extraction Methods     

Sumaira Khan  Tasneem G. Kazi  Muhammad B. Arain  Nida F. Kolachi  Jameel A. Baig  Hassan I. Afridi  Abdul Q. Shah 《洁净——土壤、空气、水》2013,41(8):808-815

Sequential extraction procedures are widely used to characterize the different operational fractions with different potential toxicity of metals in environmental solid samples. The present work describes the application of different analytical approaches for sequential extraction of aluminum to evaluate its mobility, availability, and persistent chemical forms in sediment samples of different fresh water ecosystems (lake, canal, and river). The conventional BCR three‐stage sequential extraction procedure (C‐BCR) was modified at each stage, by applying ultrasonic device (U‐BCR), in order to shorten the required shaking time of 16 h for each three steps (excluding the hydrogen peroxide digestion in step 3, which was not performed with ultrasonic bath), could be completed in 40, 50, and 45 min, respectively. The aluminum in all extracts were determination by atomic absorption spectrometry using nitrous oxide – acetylene flame. The accuracy of results obtained from C‐BCR and proposed U‐BCR was verified with literature reported values of certified sediment sample (BCR 701). The overall recoveries of aluminum obtained by proposed U‐BCR were found in the range of 96.7–113% of those values obtained with C‐BCR for all fractions. Use of ultrasonic device, provided a large saving in extraction time relative to conventional shaking. It was observed that major part of Al in real sediment samples (80–83% of total Al) were bound to residual fraction. The acid soluble fraction of aluminum extracted by 0.11 mol/L CH₃COOH has good correlation with aluminum content in corresponding water samples of each ecosystem.  相似文献   

合肥温泉之乡半汤地热成因模式及其外围地热前景探讨   总被引：1，自引：0，他引：1  

宁金野 《安徽地质》2013,(3):227-230

本文在前人勘查与研究的基础上,进一步分析研究半汤地热的热源,地热成因机制及成因模式等,进而提出了“基底隆起（正向构造）聚热型地热成因模式”形成有开发利用价值的半汤外围前景地热资源新学术观点为半汤地热外围前景地热资源勘查与评价提出指导方向靶区。利用新学术观点,试图突破就热找热原则的瓶颈和禁锢,变被动找热为主动找热,扩大地热资源勘查的视野。为加快绿色、环保,可再生的地热能源勘查步伐,开辟新途径。  相似文献   

团体粒子群与最大能量串行融合算法转换波静校正          下载免费PDF全文

刘财  卢勇旭  冯晅  刘宇巍  鹿琪 《地球物理学报》2013,56(1):239-245

估计转换波的静校正量是一个复杂的非线性问题,常规的线性静校正方法无法取得好的效果.粒子群算法是一种很好的非线性全局最优化方法,但其缺点是"早熟"现象严重.最大能量法是一种常规求取静校正量的方法,局部寻优能力强且收敛速度快是其优点,但是当地震记录含有大的静校正量时易收敛于局部极值.本文在标准粒子群算法的基础上发展出了一种改进的粒子群算法:团体粒子群算法.并且通过对Rastrigin函数的寻优实验证明了其全局寻优能力优于标准粒子群算法.同时为了解决转换波静校正问题串行融合了团体粒子群算法和最大能量法.最后,建立了含一个水平反射层的模型并合成地震记录,加入随机值作为检波点静校正量.对合成的地震数据分别利用团体粒子群和最大能量的串行融合算法、标准粒子群算法和最大能量法求取静校正量并进行静校正.结果证明串行融合算法得到的静校正量与理论值误差很小,静校正后的叠加剖面连续性较好.  相似文献   

TOPOGRAPHIC EFFECTS ON VENTIFACT DEVELOPMENT,MOJAVE DESERT,CALIFORNIA     

Julie E. Laity 《自然地理学》2013,34(2):113-132

I nvestigations into processes of ventifact formation in the east-central Mojave Desert, California confirm the importance of topography as a control in the location, orientation, and intensity of ventifact abrasion. Ventifacts in the region appear to be relict in nature and probably formed during a period that ended several thousand years ago. Comparison of groove orientations with available wind data shows that regional flow direction has not changed in the recent past. Although west to northwest winds are the most frequent and intense, and therefore dictate the regional erosion pattern, low to moderate southeasterly flow is recorded on ventifacts near the crests of hills owing to the effects of velocity acceleration. Two conditions that affect ventifact development are considered in this paper: (1) wind acceleration through topographic constrictions; and (2) wind acceleration up the windward flanks of hills. Constrictions in the Barstow-Bristol trough allowed velocity increases that resulted in ventifaction on 70–90 percent of all exposed cobbles and boulders. Velocity acceleration towards the crests of hills caused a marked increase in sand transport and resultant abrasion, as expressed by increases in groove and pit dimensions. [Key words: Aeolian geomorphology, ventifacts, Mojave Desert, California.]  相似文献   

Automatic techniques for 3D reconstruction of critical workplace body postures from range imaging data     

《ISPRS Journal of Photogrammetry and Remote Sensing》2013

The paper shows techniques for the determination of structured motion parameters from range camera image sequences. The core contribution of the work presented here is the development of an integrated least squares 3D tracking approach based on amplitude and range image sequences to calculate dense 3D motion vector fields. Geometric primitives of a human body model are fitted to time series of range camera point clouds using these vector fields as additional information. Body poses and motion information for individual body parts are derived from the model fit. On the basis of these pose and motion parameters, critical body postures are detected. The primary aim of the study is to automate ergonomic studies for risk assessments regulated by law, identifying harmful movements and awkward body postures in a workplace.  相似文献   

CMIP6与CMIP5对历史大气层顶和地表辐射收支模拟的时空对比     

万梓文  王伟  吕恒  仇培宇  李雨竹  卢阳 《气候变化研究进展》2022,18(4):468-481

基于云和地球辐射能量系统观测数据集（CERES),对比分析了耦合模式比较计划第五（CMIP5）和第六阶段（CMIP6）模拟的历史大气层顶和地表辐射收支的年际变化和空间分布,明确了多模式间不确定性大的关键区域。结果表明：在年际尺度上,除地表向上长波辐射外,CMIP6的辐射分量的集合均值较CMIP5更接近于CERES观测值,全球地表向下短波辐射的高估和大气逆辐射的低估在CMIP6中分别降低了1.9 W/m²和3.3 W/m²。除大气逆辐射外,CMIP6的辐射分量在多模式间的一致性较CMIP5提高。在北极,CMIP6对大气层顶反射短波、大气层顶出射长波和地表向下短波辐射的模拟偏差较CMIP5大。在南北纬60°,CMIP6对大气逆辐射的模拟偏差较CMIP5大。其他区域CMIP6的辐射分量更接近CERES观测值。CMIP6模拟的地表向下短波辐射和大气逆辐射的不确定性较大区域面积较CMIP5减小,但不确定性极大区域面积无变化。地表净辐射的不确定性空间分布在两代CMIP间变化甚小。青藏高原、赤道太平洋、热带雨林、阿拉伯半岛和南极洲沿海依然是地球系统模式模拟辐射收支不确定性极大的关键区域。  相似文献   

Seeking a handle on climate change: Examining the comparative effectiveness of energy efficiency improvement and renewable energy production in the United States     

《Global Environmental Change》2021

This study examines the comparative effectiveness of two important proposed solutions to climate change—energy efficiency improvement and the development and use of renewable energy sources. We focus specifically on their impacts on carbon dioxide emissions by conducting fixed effects regression analysis of panel data pertaining to U.S. states. The analysis reveals a negative relationship between both remedies and carbon dioxide emissions. Although the effects of these potential solutions are statistically equivalent, renewable energy production has a slight edge. Reflecting upon these findings and the larger environmental problem, we caution against exclusive reliance on efficiency improvement and renewable energy to the neglect of other important actions, such as lifestyle modifications. A broad range of social changes, which incorporate the remedies investigated in this paper, are needed to limit long-term global temperature increases to the desired level.  相似文献   

黄河流域夏季有效降水转化率          下载免费PDF全文

李进  李栋梁  张杰 《水科学进展》2012,23(3):346-354

利用NCEP/NCAR再分析资料及中国实测雨量资料,分析发现黄河流域夏季整层降水转化率普遍较低,因考虑到整层中应有某一气压层具有最有利的水汽输送、抬升凝结和垂直运动条件,由此将该气压层定义为有效降水转化率层(简称有效层),降水与有效层可降水量之比称为有效降水转化率。通过分析黄河流域夏季各分区垂直速度与水汽等因子,确定上、中、下游夏季有效层分别为地面~500hPa、600~400hPa、850~600hPa。对比分析表明:夏季各区平均水汽收支与降水转化率,各自在整层和有效层上的逐年演变趋势均一致,峰谷相对应,且49年间降水转化率在有效层上的数值均大于整层的。夏季有效降水转化率在青藏高原上空及中游东部最高,高原东北侧最低,旱、涝年与多年平均状况下的分布形式虽然一致,但涝年的数值明显大于旱年。  相似文献   

大力推广浅层地热能开发利用 促进崇明生态建设与环境保护     

张国坤 《上海国土资源》2012,33(2):3-4

浅层地热能开发利用是崇明生态岛建设的重要工作内容。结合崇明县经济社会发展规划,充分发挥绿色能源示范县建设的作用,推进浅层地热能开发利用管理机制建设,将促进崇明生态岛建设与环境保护。  相似文献   

A New Formation Mechanism of Coesite without the Plate Deeply-Subduction and Fast-Exhumation——Comment on the Article “Discussion on Some Problems of Quartz-Coesite Phase Transition”     

SU Wenhui  XU Dapeng 《地质论评》2012,58(2)

本文分析评论了嵇少丞等(2010)发表的“石英—柯石英相变研究中若干问题讨论”一文.指出他们对柯石英非俯冲折返新机制的一些误解,对某些热力学、物理学概念,及其在地学问题中的解释理解的不同.分析了机械球磨的作用机制;论证了机械球磨作用本质与构造挤压剪切作用本质的同一性.分析了岩石糜棱岩化过程的两个阶段;讨论了地震波形成柯石英机制的可能性.围绕比较标准问题,论证了高能机械球磨(预处理)能大大降低α-石英转变成柯石英的压力、温度和合成时间,促进柯石英的形成.用小尺度不均匀局域高压微区模型解释了人工合成柯石英的规律性、南极洲天然矿物的行为,柯石英的寄生矿物、岩石——锆石、榴辉岩包裹体、非包裹体的形成.列举事例澄清了“球磨引进的Fe杂质提高柯石英形成压力迟缓合成”的说法;讨论了第二相存在对石英—柯石英转变的影响和“应变禁区”边界区的应力梯度相变驱动力可以形成柯石英问题.指出了机械球磨石英原料预处理和静高压合成柯石英后处理两步法,是一种实验室研究柯石英形成规律的有效物理方法;小尺度不均匀局域高压微区模型和无需板块深俯冲快折返的柯石英形成机制,是一种有希望的柯石英形成新机制.  相似文献